Shade matching is done at the end of a batch usually at room temperature. When color matching foundations, it is easier to make full formula extenders instead of adding straight pigment to the base. A full formula extender is the base formula with only one pigment instead of the combination of TiO2, yellow IO, red IO, and black IO. So you would have one TiO2 formula extender, one red IO formula extender, one yellow IO formula extender, and one black IO extender. If the shade is too opaque you can use a sericite full formula extender to lose some opacity.
Tuesday, January 28, 2014
Tips on How to Correct/Shade Match Liquid Foundations
Shade matching is done at the end of a batch usually at room temperature. When color matching foundations, it is easier to make full formula extenders instead of adding straight pigment to the base. A full formula extender is the base formula with only one pigment instead of the combination of TiO2, yellow IO, red IO, and black IO. So you would have one TiO2 formula extender, one red IO formula extender, one yellow IO formula extender, and one black IO extender. If the shade is too opaque you can use a sericite full formula extender to lose some opacity.
Monday, January 27, 2014
Liquid Foundations
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Image: Link source |
Liquid foundations also use pigmentary TiO2 and iron oxides to provide color. The same ratios used in pressed powders apply to liquid foundations. An American shade is 10-12% pigmentary TiO2 and iron oxides (7% TiO2, 3% yellow iron oxide, 1.75% red iron oxide, and 0.2% black iron oxide). For much darker shades you would use much less pigmentary TiO2 (such as 1%) and a more yellow, red, and black iron oxide. A Japanese shade contains more TiO2 than an American shade, ~10% TiO2. Though the percentage of each pigment will be different in each shade, you want the overall percentage of TiO2 and pigments to be the same for each shade so each will have the same feel.
Instead of using untreated TiO2 and iron oxides, which are hydrophilic, it is much better to use treated pigments. Treated pigments are easier to incorporate into oils, esters, and silicones. However, it is even better to use pigmentary dispersions than to make your own pigment grinds. The pigment in the dispersions are already well dispersed and the particle size is made small so that the color is more intense. Smaller particles provide for increased light scattering from the increased surface area of the small pigment. Also, a higher concentration of pigment can be incorporated into a dispersion because of the surface treatment on the pigment and manufacturing of the dispersion. You also get less streaking in liquid foundations when all the pigments are wet out, especially the red. Dispersions help in many aspects.
Silicones are frequently used in liquid foundations because of the lubricous feel and slip they provide. Water in silicone foundations dry slower than oil in water foundations and have more play time. If you have water in volatile silicone though, the foundation will dry fast because the silicone evaporates as you rub it out on your skin. Water in volatile silicone foundations also feel lighter on the skin than traditional foundations that do not have volatile.
Sunscreen actives can also be incorporated into a liquid foundation if you want to claim SPF. Film former can be added for long wear. Microspheres can be added to reduce any shininess that remains after its applied not he skin. Microspheres can also improve the feel of the of the liquid foundation on skin by creating more slip and a silky feel.
Thursday, January 16, 2014
Cream to Powders
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Image: Link Source |
Thin oils and silicone are best to use in this formula. In order to have the powdery after feel, you need a large amount of powder in the formula. Usually there will be as much as 15% TiO2 and several percent iron oxides. In addition, you want to have 20-25% of fillers or microspheres. A large size microsphere will give more of a powdery feel. Always add microspheres at the end. Using surface treated materials will help you to load a high level of powders because oil absorption will be reduced. Be sure though that you are not adding so much powder that the wax structure is negatively affected. You want good structure. Because you have waxes, you want to make sure there is no sweating in the cream to powder. Absorbent microspheres will help to prevent sweating.
Here is a basic formula of a cream to powder:
Phase
|
%
|
Ingredient
|
A
|
13
|
Pigmentary TiO2 (treated)
|
A
|
6
|
Mica
|
A
|
0.33
|
Yellow IO (treated)
|
A
|
0.33
|
Red IO (treated)
|
A
|
0.1
|
Black IO (treated)
|
A
|
0.1
|
Methylparaben
|
A
|
0.1
|
Propylparaben
|
B
|
29.04
|
Propylene Glycol Dicapryl/Dicaprate
|
B
|
17
|
Dimethicone
|
B
|
9
|
Ozokerite Wax
|
C
|
25
|
Microsphere
|
100
|
Blend Part A until the color is fully developed. Heat Part B while mixing. Add Part A to Part B and mix until homogenous. Add Part C and continue to maintain temperature. Continue to mix and and then cool down a bit and pour into pans.
Tuesday, January 14, 2014
I'm back :)
Hi everyone,
Sorry that I haven't posted in months. I'm back now and will try to post regularly so please bear with me.
I appreciate the positive feedback I have received. Thank you for taking the time to read my blog! Please comment and feel free to ask any questions.
Thanks,
CosmeticChemGal
Monday, September 16, 2013
Pressed Powder Formula and Loose Powder
Here is a basic pressed powder formula:
Percentage
|
Ingredient
|
70.48%
|
Mica
|
10%
|
Methyl Methacrylate Crosspolymer (And) Polymethylsilsesquioxane
|
7%
|
Pimentary TiO2 and silicone treatment
|
2%
|
Zinc Myristate
|
1%
|
Yellow iron oxide and silicone treatment
|
0.86%
|
Red iron oxide and silicone treatment
|
0.46%
|
Black iron oxide and silicone treatment
|
0.1%
|
Propylparaben
|
0.1%
|
Methylparaben
|
2.5%
|
Dimethicone
|
2.5%
|
Propylene Glycol Dicaprylate/Dicaprate
|
2%
|
Dimethicone
|
1%
|
Dimethicone (And) Trimethylsiloxysilicate
|
100%
|
Micropulverize the powders until the color is fully developed. Then add the liquid binder to the powder and micropulverize well. Press at 500psi.
Loose powders are the same as pressed powders except for the fact that you don't have a liquid binder and you do not press it. If you find that upon application you have a lot of fly away, then you can add a couple percentage of liquid to coat the powder and make it heavy so that it doesn't fly away. Liquid may also help the loose powder feel better. You can include a film former in the liquid so that the powder adheres on the skin better.
Sunday, September 15, 2013
Pressed Powders
Image: Link source |
Talc consists of small platelets and comes in different sizes. It is easy to press because it is small platelets that slip together. Talc is found in many pressed powders because of its ability to press well. There is some concern about talc and asbestos. Talc has asbestos in its natural form but after it has been processed, etc and it is ready to be used in your product, it does not have asbestos anymore.
Mica consists of bigger platelets than talc. It doesn't press as well as talc and doesn't slip as well as talc. Large platelets are hard to press. It is shiny and transparent compared to talc. There is natural mica and there is synthetic mica. Synthetic mica has platelets that are more transparent, smooth and flat. Because synthetic mica is flat and smooth, it reflects more and acts like a mirror.
Sericite is a type of mica but it is older and more broken down. It whiter, softer, and more platey. It is also smaller and thicker than mica. Sericite is close to being a talc replacement.
There is also boron nitride, which makes a pressed powder feel very soft and silky.
The bulk of a pressed powder is fillers. There is also pigmentary TiO2 for coverage and yellow iron oxides, red iron oxides, and black iron oxides for color. Pigmentary TiO2 is different from the TiO2 that is used in sunscreen emulsions because it is much larger, greater than 0.2 microns (200 nanometers). Iron oxides are also greater than ~0.2 microns (200 nanometers). What is usually used in a American shade is 10-12% pigmentary TiO2 and iron oxides (7% TiO2, 3% yellow iron oxide, 1.75% red iron oxide, and 0.2% black iron oxide). For much darker shades you would use much less pigmentary TiO2 (such as 1%) and a more yellow, red, and black iron oxide. A Japanese shade contains more TiO2 than an American shade, ~10% TiO2.
Sunscreen actives can be used in a pressed powder if you want to claim SPF.
Microspheres are also great to add because they can absorb oil, add soft focus effect, and chance skin feel. Make sure to choose a microsphere that can be easily pressed. Microspheres that are perfectly spherical are hard to press.
Pearls can also be added for shimmer but they can be hard to press. Surface treated pearls are easier to press.
Using surface treated fillers, pigments, and microspheres are a good idea because the treatment helps the material press better. When treated the surface is smoother so they slide against each other and it is easier to press (they slip to lay flat). Another reason why it presses better is because there is less entrapped air because bulk density is higher.
Preservative is also added to pressed powder. Although pressed powders are anhydrous, water may be introduced into the pressed powder by the consumer so it is critical to have some preservative to protect against any microorganism growth.
Usually you need 6-7% binder to press. Liquid binder consists of esters, oils, or silicones depending on what is compatible with the other ingredients in your pressed powder, especially if you have surface treated material. You can include a film former in the liquid binder to help the powder adhere to skin. Dry binders, such as magnesium myristate, zinc stearate, etc, are also used to help press. Dry binders are predominately used in formulas with pearls.
Saturday, September 14, 2013
Sunscreen Formula and Formulating Tips
Now that I’ve discussed sunscreen actives, here is an example of a basic formula for a sunscreen emulsion. This formula is taken from the ChemistsCorner website which I highly recommend that you read if you aren’t already! It is a great source of cosmetic science information.
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Image: ChemistsCorner |
Sunscreens can also be anhydrous, in a spray form, and a stick form.
To figure out how much sunscreen actives you will need to reach your desired SPF, here are some GENERAL guidelines:
Organic sunscreens generally provide 2 SPF units per percentage of organic sunscreen active.
Titanium dioxide generally provides 2-3 SPF units per percentage of TiO2. You will get less SPF units if you have TiO2 with large particle size.
Zinc Oxide generally provides 0.5 to 2 SPF units per percentage of Zinc Oxide, depending on particle size.
Also keep in mind when estimating SPF:
1) There is synergy among TiO2 and ZnO and organic sunscreen actives
2) SPF boosters can help boost SPF
3) Other formula ingredients can help maximize SPF: film formers help keep sunscreen on the skin
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